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Download Chemistry Chapter 1 Test Bank Exam Questions with Verified Answers and more Exams Chemistry in PDF only on Docsity! Chemistry Chapter 1 Test Bank Exam Questions with Verified Answers 1) Which of the following best describes the origin of carbon atoms? Correct Answers - Correct Answers c) byproduct of chemical fusion in stars 3) The greatest degree of ionic character is anticipated for the bond between Correct Answers - Correct Answers b) H and Cl. 5) Select the most electronegative element from the list below. Correct Answers - Correct Answers b) O 6) Which of these substances contain both covalent and ionic bonds? Correct Answers - Correct Answers a) NH4Cl 9) In which of the following does the central atom have 2 pairs of non-bonding electrons? Correct Answers - Correct Answers e) H2S 11) Which of these is a correct electron-dot representation of the nitrite ion, NO2-? Correct Answers - Correct Answers a) I 13) Considering Lewis structures, which of these compounds possesses a single unpaired electron? Correct Answers - Correct Answers c) NO 15) Expansion of the valence shell to accommodate more than eight electrons is possible with ___. Correct Answers - Correct Answers d) sulfur 16) What is the formal charge on oxygen in the following structure? Correct Answers - Correct Answers b) +1 19) Which structure(s) contain(s) an oxygen that bears a formal charge of +1? Correct Answers - Correct Answers b) III and IV 21) Which of the following molecules or ions has a nitrogen with a formal charge of -1? Correct Answers - Correct Answers A 23) Which of the following is an ion with a negative one charge? Correct Answers - Correct Answers d) All of these choices. 25) Listed below are electron dot formulas for several simple molecules and ions. All valence electrons are shown; however, electrical charges have been omitted deliberately. Which of the structures actually bear(s) a positive charge? Correct Answers - Correct Answers e) IV and V 26) Listed below are electron dot formulas for several simple molecules and ions. All valence electrons are shown; however, electrical charges have been omitted deliberately. Which of the structures is negatively charged? Correct Answers - Correct Answers b) II 29) Which compound contains a nitrogen atom with a formal positive charge? Correct Answers - Correct Answers d) More than one of these choices. 31) CH3CH2OCH2CH3 and CH3CH2CH2CH2OH are examples of what are now termed: Correct Answers - Correct Answers e) Constitutional isomers 33) Which compound is not a constitutional isomer of the others? Correct Answers - Correct Answers d) IV 35) Which of the following represent a pair of constitutional isomers? Correct Answers - Correct Answers e) More than one of these choices. 36) Which of the following represent pairs of constitutional isomers? Correct Answers - Correct Answers e) All of these pairs. 39) Which compound is not a constitutional isomer of the others? Correct Answers - Correct Answers c) III 41) Which of the following pairs are NOT resonance structures? Correct Answers - Correct Answers C 43) Which of the following species is a resonance form of the species in the box? Correct Answers - Correct Answers c) III 45) Which of the following species is not a resonance form of the following species? Correct Answers - Correct Answers A 46) Which of the following species is/are a resonance form(s) of the species in the box? Correct Answers - Correct Answers d) II 49) Which of the following species is/are not a resonance form(s) of the species in the box? Correct Answers - Correct Answers a) I 51) Which of the following species contributes more to the overall hybrid for the species in the box? Correct Answers - Correct Answers c) III 106) Identify the atomic orbital the lone pair electrons on the C atom are contained in: Correct Answers - Correct Answers b) 2sp2 109) The following electron configuration represents: Correct Answers - Correct Answers e) None of these choices correctly identifies the given electron configuration. 111) Identify the atomic and/or hybridized orbitals in the C-O sigma bond in acetone. Correct Answers - Correct Answers a) (2sp2, 2sp2) 113) Which molecule has a non-linear shape (i.e., for which molecule are the nuclei not in a straight line)? Correct Answers - Correct Answers b) H-O-H 115) What is the geometry of the C indicated with the arrow? Correct Answers - Correct Answers e) original planar 116) What geometry does the methyl action, CH3+, have? Correct Answers - Correct Answers c) original planar 119) The bond angles for the bold-faced C in CH3CH2CH2+ would be expected to be approximately: Correct Answers - Correct Answers e) 120 121) What bond angle is associated with a tetrahedral molecule? Correct Answers - Correct Answers b) 109.5 123) VSEPR theory predicts an identical shape for all of the following, except: Correct Answers - Correct Answers c) BH3 125) Which of these structures would be a perfectly regular tetrahedron? Correct Answers - Correct Answers d) CBr4 126) The bond angle for the C-C-O bonds in the following compound would be expected to be approximately: Correct Answers - Correct Answers e) 120 129) The bond angle for the C-N-O bonds in the following molecule would be expected to be approximately: Correct Answers - Correct Answers c) 120 131) The bond angle for the C-C-N bonds in CH3CN would be expected to be approximately: Correct Answers - Correct Answers e) 180 133) Based on the VSEPR theory, which of the following would have a tetrahedral arrangement of electrons around the central atom? Correct Answers - Correct Answers c) SiH4 135) What is the geometry around the N in the following molecule? Correct Answers - Correct Answers c) linear 136) Which molecule would be linear? (In each case you should write a Lewis structure before deciding.) Correct Answers - Correct Answers b) HCN

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